Other forms: unbuckled; unbuckling; unbuckles
To unbuckle is to release a belt or clasp — to unfasten. You're going to have to unbuckle your seat belt before you get out of the car.
The verb unbuckle adds the prefix un- (""reverse of") to buckle, which stems from the Latin word buccula, "cheek strap of a helmet." So just as you buckle your helmet before you jump on your bike, you unbuckle it once you arrive at your friend's house.