Other forms: plenipotentiaries
An ambassador who independently represents their home country in another country can be called a plenipotentiary.
The word plenipotentiary comes from Latin roots, plenus, "complete or full," and potentem, "powerful." Someone who is a plenipotentiary literally has full powers to represent their government — the prime minister or president has officially authorized them to sign treaties or other agreements on behalf of that government. Some (but not all) diplomats are plenipotentiaries.