The adverb inherently means in a natural or innate manner. Some people enjoy your inherently cheerful nature, but it drives other people crazy because they find you annoyingly perky.
Inherently is the adverbial form of the adjective inherent. They both come from the Latin word inhaerere, meaning "adhere to," with the root haerere meaning "to stick." Synonyms for inherently include intrinsically and essentially. If you do something inherently, it is so well ingrained in you that it's become part of who you are. If you are inherently late to every meeting, you should probably set your watch 15 minutes early.